2,2-联吡啶-4,4-（5-己基-2-噻吩）合成路线 （共 5 条）
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran; water 40 h; Reflux;
参考文献
UTI LIMITED PARTNERSHIP; BERLINGUETTE, Curtis; BOMBEN, Paolo
Patent: WO2012/155247 A1, 2012 ;
Location in patent: Page/Page column 77 ;
反应条件
Pd2(PPh3)2Cl2 in N,N-dimethyl-formamide T=85°C; 12 h; Inert atmosphere;
参考文献
Neuthe, Katja; Bittner, Florian; Stiemke, Frank; Ziem, Benjamin; Du, Juan; Zellner, Monika; Wark, Michael; Schubert, Thomas; Haag, Rainer
Dyes and Pigments, 2014 , vol. 104, p. 24 - 33
反应条件
1: 2-(1-hexyl)thiophene With n-butyllithium in tetrahydrofuran; hexane T=-78 - 20°C; 2 h; Inert atmosphere; 2: With tributyltin chloride in tetrahydrofuran; hexane T=20°C; 4 h; Inert atmosphere; 3: bipy-Br2 With bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=85°C; Inert atmosphere;
参考文献
Gao, Feifei; Wang, Yuan; Shi, Dong; Zhang, Jing; Wang, Mingkui; Jing, Xiaoyan; Humphry-Baker, Robin; Wang, Peng; Zakeeruddin, Shaik M.; Graetzel, Michael
Journal of the American Chemical Society, 2008 , vol. 130, # 32 p. 10720 - 10728
反应条件
1.1: n-butyllithium / tetrahydrofuran / 0.75 h / -70 °C 1.2: 18 h / 25 °C 2.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 40 h / Reflux View Scheme
参考文献
UTI LIMITED PARTNERSHIP; BERLINGUETTE, Curtis; BOMBEN, Paolo
Patent: WO2012/155247 A1, 2012 ;
反应条件
1.1: N-bromosuccinmide / chloroform; acetone / 16 h / 0 - 20 °C 2.1: n-butyllithium / tetrahydrofuran / 0.75 h / -70 °C 2.2: 18 h / 25 °C 3.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 40 h / Reflux View Scheme
参考文献
Neuthe, Katja; Bittner, Florian; Stiemke, Frank; Ziem, Benjamin; Du, Juan; Zellner, Monika; Wark, Michael; Schubert, Thomas; Haag, Rainer
Dyes and Pigments, 2014 , vol. 104, p. 24 - 33
