hydroboration;

9-bora-bicyclo[3.3.1]nonane in tetrahydrofuran T=85 - 90°C; 18 h;

in 1,4-dioxane

potassium carbonate; dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) in tetrahydrofuran; N,N-dimethyl-formamide To a soln. of 9-((CH2)10CO2CH3)-9-BBN is added CH3O2C(C6H4)I, THF-DMF and pwd. K2CO3, mixt. is stirred for 8 h at 50°C, poured into water.; Extracted with benzene, washed with water, dried (MgSO4), final product is identified by mass spectrometry, IR, elem. anal.;

N,N,N',N',N'',N''-hexamethylphosphoric triamide; Zn(II)(acetylacetonate)2; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=50 - 55°C; P=760 Torr; 24 h;

potassium phosphate; tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane T=60°C; var. primary iodoalkanes and 9-alkyl-9-BBN derivatives; Product distribution;

potassium phosphate; tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane T=60°C; 67 h;