(1S,3S,4R)-对薄荷-8-烯-3-醇合成路线 (共 32 条)
反应条件
ATPH in toluene T=5°C; 5 h;
参考文献
TAKASAGO INTERNATIONAL CORPORATION
Patent: US2010/324338 A1, 2010 ;
Location in patent: Page/Page column 64 ;
反应条件
triethylaluminum; (R)-2,2'-dihydroxy-1,1'-binaphthyl in toluene T=0 - 5°C; 9 h; Inert atmosphere; Product distribution / selectivity;
参考文献
Takasago International Corporation
Patent: EP2279992 A1, 2011 ;
Location in patent: Page/Page column 13 ;
反应条件
ytterbium (III) tris-[tris-(nonafluorobutanesulfonyl)methide] in dichloromethane T=-78°C; 3 h;
参考文献
US6664380 B1, ;
Page column 21 ;
反应条件
H-Beta-11 in cyclohexane T=90°C; P=7500.6 Torr; 3 h; Product distribution; Further Variations:Reagents;
参考文献
Maeki-Arvela, Paeivi; Kumar, Narendra; Nieminen, Ville; Sjoeholm, Rainer; Salmi, Tapio; Murzin, Dmitry Yu.
Journal of Catalysis, 2004 , vol. 225, # 1 p. 155 - 169
反应条件
sodium hydroxide in N-dodecane; toluene
反应条件
[(n-Bu)4N]3[γ-SiW10O36{Al(OH)2}(μ-OH)2]*4H2O in acetonitrile T=75°C; 10 h; Inert atmosphere; diastereoselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 130, # 47 p. 15872 - 15878
反应条件
1 Pd/C; hydrogen in hexane T=49.84°C; P=7500.75 Torr; 6 h; regioselective reaction;
参考文献
Chemical Communications, , # 34 p. 4058 - 4060
反应条件
pyridine T=140°C; 216 h;
参考文献
Murphy, William S.; Culhane, Anne; Duffy, Brian; Tuladhar, Sudersan Man
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 24 p. 3397 - 3400
反应条件
diiodosamarium in dichloromethane 24 h; Ambient temperature;
参考文献
Tetrahedron Letters, , vol. 37, # 29 p. 5195 - 5198
反应条件
(S,S)-1-NAPHTADDOL aluminum complex in toluene T=0 - 5°C; 7 h; Inert atmosphere; Product distribution / selectivity;
参考文献
WO2010/71231 A1, ;
Page/Page column 48-49 ;