1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
in further solvent(s) (under exclusion of moisture); refluxing in S2Cl2 at 160°C for 5 h; ppt. filtered, washed (CHCl2);
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 520, p. 7 - 17
反应条件
byproducts: S(x)Cl2; (N2), bomb reed, heated at 250°C for 24 h; cooled in liquid air in vac., distd.;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 553, p. 239 - 247
反应条件
(N2), bomb reed, heated at 205°C for 60 h; cooled in liquid air in vac. for a week, distd.; Raman spectr.;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 553, p. 239 - 247
反应条件
in neat (no solvent) reaction starts 10-20 min after the introduction of chlorine began; room temp. (higher pressure of chlorine accelerates reaction);;
参考文献
S: MVol.B3, 106, page 1761 - 1762
反应条件
reaction of WCl2 with S under a vacuum at 350°C for 3 d; removal of the S2Cl2 byproduct by condensation, removal of excess S by heating under a dynamic vacuum; elem. anal.;
参考文献
Journal of Alloys and Compounds, , vol. 182, # 2 p. 253 - 264
反应条件
more SO2 forms explosionlike;
参考文献
Journal of Chemical Education, , vol. 36, p. 58 - 59
S: SVol.3, 2.1.8.10.4, page 214 - 214
反应条件
in neat (no solvent) dry box; dissolving S in Se2Cl2 by heating several min; further products; not isolated; detn. by Raman- and (77)Se-NMR spectroscopy;
参考文献
Milne, John B.
Canadian Journal of Chemistry, 1992 , vol. 70, # 3 p. 693 - 699
反应条件
in carbon disulfide byproducts: I2; 25°C; evapn. of solvent, removing I2 in vac. at 50°C; distn. in vac.;
参考文献
Schmidt, M.; Siebert, W.; Rittig, F.
Chemische Berichte, 1968 , vol. 101, p. 281 - 284
反应条件
NH3 in ammonia NH3 (liquid); inert atmosphere;
参考文献
O'Mahoney, Caroline A.; Parkin, Ivan P.; Williams, David J.; Woollins, J. Derek
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 1179 - 1186
反应条件
190 and 210 degree.C;
参考文献
Schmidt, M.; Dersin, H. J.; Schumann, H.
Chemische Berichte, 1962 , vol. 95, p. 1428 - 1433
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.4.3, page 156 - 157
