1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
in gaseous matrix Ar discharge (stream of Ar/S8 2-3 mmol/h), annealing (32+/-2 K); further products; not isolated; trapped in solid argon; IR;
参考文献
Mielke, Zofia; Brabson, G. Dana; Andrews, Lester
Journal of Physical Chemistry, 1991 , vol. 95, # 1 p. 75 - 79
反应条件
in gaseous matrix Ar discharge, annealing (32+/-2 K); further products; not isolated; trapped in solid argon; IR;
参考文献
Mielke, Zofia; Brabson, G. Dana; Andrews, Lester
Journal of Physical Chemistry, 1991 , vol. 95, # 1 p. 75 - 79
反应条件
in carbon disulfide byproducts: S9; in a sealed ampoule; 130-155°C; quenched with ice-water; HPLC;
参考文献
Tebbe, Fred N.; Wasserman, E.; Peet, William G.; Vatvars, Arturs; Hayman, Alan C.
Journal of the American Chemical Society, 1982 , vol. 104, p. 4971 - 4972
反应条件
in carbon disulfide Kinetics; byproducts: cyclo-S5, S9; Irradiation (UV/VIS); photolysis (high-pressure Hg lamp, 200-600 nm), 15°C; monitoring by HPL chromy.;
参考文献
Strauss, Eva-Maria; Steudel, Ralf
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1987 , vol. 42, # 6 p. 682 - 690
反应条件
in benzene 80°C, 6 h, treated with 5percent hydrochlorid acid; extrd. with ether, distd. in vac.;
参考文献
Dzhemilev, U. M.; Ibragimov, A. G.; Zolotarev, A. P.; Tolstikov, G. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 6.2 p. 1324
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , # 6 p. 1444
反应条件
in tetrahydrofuran adding ((iPrCp)2TiCl)2 in THF to freshly sublimated S8 under stirring at room temp. , react. time: 3d ; argon atmosphere, equil.; flash chromatography, elem. anal.;
参考文献
Tainturier, G.; Gautheron, B.
Phosphorus and Sulfur and the Related Elements, 1988 , vol. 36, p. 11 - 14
反应条件
in toluene reflux, 20 h; preparative TLC (silica gel, benzene/hexane);
参考文献
Tsumuraya, Takeshi; Sato, Sadao; Ando, Wataru
Organometallics, 1988 , vol. 7, p. 2015 - 2019
反应条件
in cyclohexane Irradiation (UV/VIS); irradiation with a low-pressure mercury lamp for 5 h at room temp.; evapn. of solvent under reduced pressure, sepn. by flash column chromy. (silica gel, benzene/hexane, N2 pressure); elem. anal.;
参考文献
Tsumuraya, Takeshi; Sato, Sadao; Ando, Wataru
Organometallics, 1988 , vol. 7, p. 2015 - 2019
反应条件
in benzene heating to 50°C with an excess of sulfur; 2,4-digerma-1,3-dithietane is characterized by comparison to an authentic sample; metadithiophosphonate is characterized by NMR;
参考文献
Andrianarison, Mbolatiana; Couret, Claude; Declercq, Jean-Paul; Dubourg, Antoine; Escudie, Jean; et al.
Organometallics, 1988 , vol. 7, p. 1545 - 1548
反应条件
byproducts: S(x)Cl2; (N2), bomb reed, heated at 250°C for 24 h; cooled in liquid air in vac., distd.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
