1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
in liquid sulphur dioxide
in autoclave, 40-50°C, 6 h;
参考文献
Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.5, page 172 - 209
反应条件
in liquid sulphur dioxide
in autoclave, 100°C, 6 h;
参考文献
Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.5, page 172 - 209
反应条件
in further solvent(s)
in tetramethylenesulfone, 120°C;
参考文献
Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.5, page 172 - 209
反应条件
in sulfur dioxide
1 d; slow removal of solvent, cooling to 0°C;
参考文献
Brownridge, Scott; Cameron, T. Stanley; Passmore, Jack; Schatte, Gabriele; Way, Todd C.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 12 p. 2553 - 2570
反应条件
in decalin
soln. germane and S8 in decalin was heated at reflux temp. for 5 d; solvent was removed in vacuo, residue was purified by GPLC andrecrystd. from CHCl3-hexane; elem. anal.;
参考文献
Goto, Kei; Shimo, Isao; Kawashima, Takayuki
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 12 p. 2389 - 2394
反应条件
in liquid sulphur dioxide
C2F4, SbF5 and S8 molar ratio = 2.5:1, in autoclave at 20°C, 6 h;
参考文献
Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.5, page 172 - 209
反应条件
in benzene
byproducts: 1,4-di(trimethylsilyl)-2,3,6,7-tetrathiacyclooctan, 1-methyl-3-trimethylsilyl-2,5-dithiacyclopentane; mixt. of educts in benzene stirred at 55°C for 8 h; evapd. in vac., extd. with pentane, evapd., chromd. (SiO2, hexane);
参考文献
Chernyshev, E.A.; Kuz'Min, O.V.; Lebedev, A.V.; Gusev, A.I.; Kirillova, N.I.; et. al.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 2 p. 133 - 142
反应条件
in benzene
byproducts: Me3SiCHCH2SCH2CH(SiMe3)S2, Me3SiCHCH2S2CH2CH(SiMe3)S2; mixt. of educts in benzene stirred at 55°C for 8 h; evapd. in vac., extd. with pentane, evapd., chromd. (SiO2, hexane), dissolved in benzene, refluxed with stirring for 4 h, evapd., crystd. from ethanol, recrystd. from hexane; elem. anal.;
参考文献
Chernyshev, E.A.; Kuz'Min, O.V.; Lebedev, A.V.; Gusev, A.I.; Los', M.G.; et. al.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 2 p. 143 - 148
反应条件
in benzene
byproducts: 1,4-di(trimethylsilyl)-2,3,6,7-tetrathiacyclooctan, 1-methyl-3-trimethylsilyl-2,5-dithiacyclopentane; mixt. of educts in benzene stirred at 55°C for 8 h; evapd. in vac., extd. with pentane, evapd., chromd. (SiO2, hexane);
参考文献
Chernyshev, E.A.; Kuz'Min, O.V.; Lebedev, A.V.; Gusev, A.I.; Kirillova, N.I.; et. al.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 2 p. 133 - 142
反应条件
in tetrahydrofuran
N2 atmosphere; stirring (20°C, 2 h); solvent removal (vac.), extraction (n-pentane, ArPS2 sepn.), product Fe-complexes not sepd. from mixt. with educt Fe-complex, identified with (31)P-NMR;
参考文献
Weber, Lothar; Meine, Georg; Boese, Roland; Niederpruem, Norbert
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1988 , vol. 43, # 6 p. 715 - 721
