1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
参考文献
Siebert,W. et al.
Journal of Organometallic Chemistry, 1970 , vol. 23, p. 329 - 342
反应条件
(N2), bomb reed, heated at 145°C for 20 h; cooled in liquid air in vac., distd.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
反应条件
(N2), bomb reed, heated at 205°C for 60 h; cooled in liquid air in vac. for a week, distd.; Raman spectr.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
反应条件
aluminium trichloride
(N2), bomb reed, heated at 205°C for 60 h; cooled in liquid air in vac., distd.; Raman spectr.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
反应条件
aluminium
byproducts: CH3SCH3; (N2), bomb reed, heated at 270°C for 45 h; cooled in liquid air in vac., distd.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
反应条件
aluminium
(N2), bomb reed, heated at 250°C for 14 h; cooled in liquid air in vac., distd.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
反应条件
(N2), bomb reed, heated at 245°C for 66 h; cooled in liquid air in vac., distd.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
反应条件
byproducts: CH3SCH3, CH3SSCH3, (CH3)3SBr; (N2), bomb reed, heated at 250°C for 66 h; cooled in liquid air in vac., distd.;
参考文献
Schmidt, M.; Froehlich, B.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 553, p. 239 - 247
反应条件
(.eta.5-C5Me5)2Mo2(mu.-S)2(.mu.-SH)2 in chlorobenzene; butan-1-ol
Kinetics; in 1:1 PhCl-n-BuOH (75°C, 2.4 atm H2);
参考文献
Kubas, Gregory J.; Ryan, R. R.
Journal of the American Chemical Society, 1985 , vol. 107, p. 6138 - 6140
反应条件
in deuterated toluene
Kinetics; byproducts: H2S; (N2); using Schlenk techniques; dissolving of (EtC5Me4)ReCl2(SCH2CH2S) in toluene-d8, filtration, placing into NMR tube, freezing, evacuating, addn. of large excess of S8, degassing, sealing, heating to 70°C for several days; identification by NMR;
参考文献
Kanney; Noll; DuBois, M. Rakowski
Journal of the American Chemical Society, 2002 , vol. 124, # 33 p. 9878 - 9886
