1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
in dichloromethane inert atmosphere; addn. of HgPh(S7N) to suspn. of Pd-complex (stirring, 4 h, room temp.); filtration (Celite), redn. of vol. (vac.), chromy. (column, CH2Cl2), evapn. (slow); elem. anal.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1179 - 1186
反应条件
in liquid sulphur dioxide S8(AsF6)2 in SO2 was added onto KI, stirred for 2 h at room temp., filtered, SO2ClF was added; volatiles were removed;
参考文献
Inorganic Chemistry, , vol. 20, p. 3839 - 3845
反应条件
in tetrahydrofuran byproducts: CO; (exclusion of air, moisture and light); addn. of the Ti complex in THF to the org. compd. in THF over 1 h, stirring (20°C, 15 h); concn., repeated column chromy. (SiO2; tBuOMe/hexane), not obtained fully pure;
参考文献
Chemische Berichte, , vol. 130, # 6 p. 757 - 764
反应条件
in neat (no solvent) Kinetics; byproducts: H2O; mixture of pure, dry gases (SO2:H2S = 1:2) at 21°C partial pressures 44.8 and 89.6 Torr, investigation of pressure at 308°C, quartz vessel, no acceleration by glass wool;;
参考文献
Kautschuk, , vol. 10, p. 82 - 83
S: MVol.B1, 129, page 281 - 283
参考文献
Sodium Borohydride, Potassium Borohydride, Beverly, Mass., 1958, S. 18
反应条件
in hydrogenchloride with 0.1 to 0.001 M HCl at about 80°C;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 33, p. 1052 - 1057
S: SVol.4a/b, 1.1.5.3.3, page 32 - 35
反应条件
in carbon disulfide Kinetics; byproducts: S9, S5; Irradiation (UV/VIS); photolysis (high pressure Hg lamp, 200-600 nm), 15°C; monitoring by HPL chromy.;
参考文献
Zeitschrift fuer Naturforschung, B: Chemical Sciences, , vol. 42, # 6 p. 682 - 690
反应条件
in hydrogenchloride with 0.1 to 0.001 M HCl at about 80°C;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 33, p. 1052 - 1057
S: SVol.4a/b, 1.1.5.3.3, page 32 - 35
反应条件
in neat (no solvent) educt sealed under Ar heated at heating rate of 7.5 K/min up to 453-463 K; solid dissolved in CCl4, identified by TLC and with gas chromatograph;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 60, # 7 p. 2391 - 2394
参考文献
B: B-Verb.3, 2.5.1.2, page 17 - 18
unveroeffentlich (1975)
