1: With methyl-diethoxy-silane; Rh<(S,S)-Phebox-i-Pr>(OAc)2(aq) in toluene T=60°C; 2: With potassium fluoride; tetrabutyl ammonium fluoride in tetrahydrofuran; methanol; toluene Further stages.;
diisobutylaluminium hydride in dichloromethane; toluene T=-78°C; 1.5 h; Inert atmosphere;
参考文献
West, Thomas H.; Daniels, David S. B.; Slawin, Alexandra M. Z.; Smith, Andrew D.
Journal of the American Chemical Society, 2014 , vol. 136, # 12 p. 4476 - 4479
1: dichloromethane / 20 - 25 °C / |Inert atmosphere 2: diisobutylaluminium hydride / dichloromethane; toluene / 1.5 h / -78 °C / |Inert atmosphere View Scheme
参考文献
West, Thomas H.; Daniels, David S. B.; Slawin, Alexandra M. Z.; Smith, Andrew D.
Journal of the American Chemical Society, 2014 , vol. 136, # 12 p. 4476 - 4479