1: With titanium(IV) isopropylate; tert.-butylhydroperoxide; D-(-)-diisopropyl tartrate in dichloromethane
Sharpless epoxidation;
2: With sodium bis(2-methoxyethoxy)aluminium dihydride in toluene
Reduction; ring cleavage;
titanium silicate; dihydrogen peroxide in water
T=59.84°C; 24 h;
参考文献
Schofield, Lee J.; Kerton, Owain J.; McMorn, Paul; Bethell, Donald; Ellwood, Simon; Hutchings, Graham J.
Journal of the Chemical Society, Perkin Transactions 2, 2002 , # 8 p. 1475 - 1481
epoxysulfonyl fluoride in various solvent(s)
T=-82 - -78°C; 0.166667 h;
参考文献
Vlad, P. F.; Ungur, N. D.; Nguen Van Hung; Perutsky, V. B.
Russian Chemical Bulletin, 1995 , vol. 44, # 12 p. 2391 - 2403
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 12 p. 2494 - 2506
