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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
对溴甲苯
合成路线
(共 1677 条)
120-93-4
2-咪唑烷酮
+
106-38-7
对溴甲苯
→
反应条件
5584-36-1
反应条件
potassium carbonate; N,N'-dimethylcyclohexane-1,2-diamine; copper(l) iodide in toluene Goldberg-Buchwald-Nandakumar reaction; 24 h; Heating;
参考文献
Lee, Chung-Chieh; Wang, Po-Shih; Viswanath, M. Balaji; Leung, Man-Kit
Synthesis, 2008 , # 9 art. no. F22607SS, p. 1359 - 1366
106-38-7
对溴甲苯
→
反应条件
55883-45-9
反应条件
1: (bromination) 2: NaI / acetone View Scheme
参考文献
Ko,E.C.F.; Leffek,K.T.
Canadian Journal of Chemistry, 1970 , vol. 48, p. 1865 - 1868
3796-70-1
香叶基丙酮
+
106-38-7
对溴甲苯
→
反应条件
55968-43-9
反应条件
lithium 1.) ether, 1 h, 2.) 1 h; Yield given. Multistep reaction;
参考文献
Sabharwal; Singh; Kad
Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, 1990 , vol. 29, # 6 p. 561 - 561
23153-73-3
+
106-38-7
对溴甲苯
→
反应条件
56005-43-7
反应条件
1: para-bromotoluene With magnesium in diethyl ether 0.333333 h; Heating; 2: ethyl 1,4-dioxaspiro[4,4]nonane-6-carboxylate in diethyl ether 1 h; Heating; 3: With hydrogenchloride in methanol; water 5 h; Heating;
参考文献
Wang, Jingli; Zhao, Linxiang; Wang, Rui; Lu, Min; Chen, Duo; Jing, Yongkui
Bioorganic and Medicinal Chemistry, 2005 , vol. 13, # 4 p. 1285 - 1291
32387-21-6
+
106-38-7
对溴甲苯
→
反应条件
51358-08-8
反应条件
C46H48N6O5Pd; potassium acetate in N,N-dimethyl acetamide T=160°C; 24 h; Inert atmosphere;
参考文献
Nandi, Debkumar; Jhou, Yang-Ming; Lee, Jhen-Yi; Kuo, Bing-Chiuan; Liu, Chien-Yu; Huang, Pei-Wen; Lee, Hon Man
Journal of Organic Chemistry, 2012 , vol. 77, # 20 p. 9384 - 9390
603-76-9
+
65610-58-4
+
106-38-7
对溴甲苯
→
反应条件
51358-08-8
+
1207427-18-6
反应条件
palladium diacetate; potassium carbonate; PCy3∙HBF4; 2,2,2-trimethylacetic acid in N,N-dimethyl acetamide T=100°C; 8 h; Inert atmosphere;
参考文献
Liegault, Benoit; Petrov, Ivan; Gorelsky, Serge I.; Fagnou, Keith
Journal of Organic Chemistry, 2010 , vol. 75, # 4 p. 1047 - 1060
603-76-9
+
106-38-7
对溴甲苯
→
反应条件
51358-08-8
+
154796-08-4
+
130162-56-0
反应条件
palladium diacetate; potassium carbonate; PCy3∙HBF4; 2,2,2-trimethylacetic acid in N,N-dimethyl acetamide T=100°C; Inert atmosphere;
参考文献
Liegault, Benoit; Petrov, Ivan; Gorelsky, Serge I.; Fagnou, Keith
Journal of Organic Chemistry, 2010 , vol. 75, # 4 p. 1047 - 1060
603-76-9
+
106-38-7
对溴甲苯
+
124589-41-9
→
反应条件
51358-08-8
+
1207427-17-5
反应条件
palladium diacetate; potassium carbonate; PCy3∙HBF4; 2,2,2-trimethylacetic acid in N,N-dimethyl acetamide T=100°C; 8 h; Inert atmosphere;
参考文献
Liegault, Benoit; Petrov, Ivan; Gorelsky, Serge I.; Fagnou, Keith
Journal of Organic Chemistry, 2010 , vol. 75, # 4 p. 1047 - 1060
106-38-7
对溴甲苯
→
反应条件
5161-04-6
反应条件
1: (i) Mg, (ii) /BRN= 605330/ 2: (dehydration) 3: H2 / Raney-Ni View Scheme
参考文献
Ruechardt,C.
Chemische Berichte, 1961 , vol. 94, p. 2609 - 2623
124-13-0
+
106-38-7
对溴甲苯
→
反应条件
51770-83-3
反应条件
1: para-bromotoluene With magnesium in tetrahydrofuran T=20°C; 1 h; 2: Caprylic Aldehyde in tetrahydrofuran T=0 - 20°C; 2 h; 3: With 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; potassium carbonate in tetrahydrofuran; tert-butyl alcohol 20 h; RefluxDarkness;
参考文献
Dohi, Souya; Moriyama, Katsuhiko; Togo, Hideo
Tetrahedron, 2012 , vol. 68, # 32 p. 6557 - 6564
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