H-mordenite zeolite (Si/Al ratio of 41.6, Na level of 130 ppm) mixed with alumina, pore forming reagent and extruded to form 1/12-inch cylindrical pellets (80percent sieve/20percent binder), calcined, mixed with ammonium heptamolybdate/water; impregnated catalyst (2percent Mo) calcined at 500° C. (1-3 h); macropore volume (>50 nm) = 0.280 cc/g T=359.99°C; P=11103.3 Torr; Product distribution / selectivity;
meta-chloroperoxybenzoic acid; tri-n-butyl-tin hydride in benzene T=90°C; 12 h; in the presence of α-iodotoluene (competitor), relative reactivity; Mechanism;
参考文献
Journal of the American Chemical Society, , vol. 102, # 2 p. 692 - 697
