1: para-xylene With tert.-butylhydroperoxide; N-bromosuccinmide in neat (no solvent)
2 h;
2: morpholine With sulfur in neat (no solvent)
T=120°C; 24 h;
1: 83 percent / AlCl3 / CH2Cl2 / 2.33 h / 10 - 20 °C
2: 79 percent / pyridine; KMnO4 / H2O / 5 h / Heating
View Scheme
参考文献
Hibbs, Michael R.; Vargas, Marian; Holtzclaw, Jeremy; Rich, Wendy; Collard, David M.; Schiraldi, David A.
Macromolecules, 2003 , vol. 36, # 20 p. 7543 - 7551
