1: propyl bromide With iron (III) acetylacetonate; magnesium in tetrahydrofuran 2: 2-chloro-3,5-dimethylpyrazine With 1-methyl-pyrrolidin-2-one T=0°C; 0.25 h;
参考文献
Dickschat, Jeroen S.; Wickel, Susanne; Bolten, Christoph J.; Nawrath, Thorben; Schulz, Stefan; Wittmann, Christoph
European Journal of Organic Chemistry, 2010 , # 14 p. 2687 - 2695
in diethyl ether (Ar), stannane added to the Grignard prepared from Mg and C3H7Br in Et2O, refluxed for 3 h; hydrolyzed with satd. NH4Cl soln., diluted with ether, org. layer sepd., washed with water for 3 times, dried over MgSO4, solvent evapd. under reduced pressure;
参考文献
Farah, Dan; Karol, Thomas J.; Kuivila, Henry G.
Organometallics, 1985 , vol. 4, p. 662 - 666
