甲基2-(3-氧代丙基)苯甲酸酯合成路线 （共 15 条）
反应条件
1: sulfuric acid / 36 h / |Reflux
2: pyridinium chlorochromate; silica gel / dichloromethane / 20 °C
View Scheme
参考文献
Zhao, Jin; Dong, Hong-Bo; Yang, Ming-Yan; Du, Juan; Jiang, Jia-Zheng; Wang, Ming-An
Journal of Asian Natural Products Research, 2014 , vol. 16, # 3 p. 312 - 317
反应条件
1: methanol; toluene; diethyl ether / 2 h / |Inert atmosphere; |Schlenk technique
2: hydrogen; Rh(acetylacetonate)(CO)2; C75H54N4O8P2 / dichloromethane / 25 h / 30 °C / 15001.5 Torr / |Inert atmosphere; |Autoclave
View Scheme
参考文献
Dydio, Pawel; Reek, Joost N. H.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 14 p. 3878 - 3882
Angew. Chem., 2013 , vol. 125, # 14 p. 4132
反应条件
N,N'-bis(salicylidene)ethylenediaminatocobalt(III) hydroxide; oxygen
1 h;
参考文献
Nishinaga, Akira; Yamazaki, Shigekazu; Matsuura, Teruo
Tetrahedron Letters, 1986 , vol. 27, # 23 p. 2649 - 2652
反应条件
1: 46 percent / n-BuLi / diethyl ether
2: 90 percent / KOH / methanol
View Scheme
参考文献
Roux; Paugam; Rousseau
Journal of Organic Chemistry, 2001 , vol. 66, # 12 p. 4304 - 4310
反应条件
1.1: ethanol / 0.75 h / 20 °C / |Schlenk technique
1.2: 0.75 h / 0 - 20 °C
2.1: trimethylaluminum / tetrahydrofuran; n-heptane / 48 h / 0 - 70 °C / |Schlenk technique
View Scheme
参考文献
Dydio, Pawel; Reek, Joost N. H.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 14 p. 3878 - 3882
Angew. Chem., 2013 , vol. 125, # 14 p. 4132
