NaOH in diethyl ether; water addn. of aq. NaOH to a cooled soln. of (CH3)3SiF in ether under vigorous stirring (neutral soln.);; drying of the ether phase; evapn. of ether; distn. of the residue;;
water; triethylamine; triphenylphosphine; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in tetrahydrofuran T=160°C; P=51485.6 Torr; 4 h; other phosphine ligand, other rhodium complex, other temp., other additives, other solv.; Product distribution;
参考文献
Takeuchi, Ryo; Yasue, Hiroyuki
Journal of Organic Chemistry, 1993 , vol. 58, # 20 p. 5386 - 5392
1: With 4-methylmorpholine N-oxide in toluene; acetonitrile T=-10°C; 0.5 - 1 h; 2: With ammonia; water in toluene; acetonitrile Product distribution / selectivity;
potassium hydroxide in potassium hydroxide; acetone byproducts: triphenylmethane; boiling of (CH3)3SiC(C6H5)3 with 40percent aq. KOH in acetone for a longer period of time;;
参考文献
Gilman, H.; Brook, A. G.; Miller, L. S.
Journal of the American Chemical Society, 1953 , vol. 75, p. 4531 - 4534
