in benzonitrile Kinetics; byproducts: benzyl phenyl ether; Sn compd. and org. compd. dissolved in benzonitrile with the addn. of small amount of CH2Cl2, sealed in glass tubes, heated at 120°C for24 h; products not isolated, detected by NMR;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 1 p. 307 - 308
in benzonitrile Kinetics; byproducts: C6H5CH2O(C6H4)CH3-p; Sn compd. and org. compd. dissolved in benzonitrile with the addn. of small amount of CH2Cl2, sealed in glass tubes, heated at 120°C; products not isolated, detected by NMR;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 1 p. 307 - 308
in benzonitrile Kinetics; byproducts: C6H5CH2O(C6H4)Cl-p; Sn compd. and org. compd. dissolved in benzonitrile with the addn. of small amount of CH2Cl2, sealed in glass tubes, heated at 120°C; products not isolated, detected by NMR;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 1 p. 307 - 308
in benzonitrile Kinetics; byproducts: C6H5CH2O(C6H4)NO2-p; Sn compd. and org. compd. dissolved in benzonitrile with the addn. of small amount of CH2Cl2, sealed in glass tubes, heated at 120°C; products not isolated, detected by NMR;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 1 p. 307 - 308
in benzonitrile Kinetics; byproducts: C6H5CH2O(C6H4)OCH3-p; Sn compd. and org. compd. dissolved in benzonitrile with the addn. of small amount of CH2Cl2, sealed in glass tubes, heated at 120°C; products not isolated, detected by NMR;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 1 p. 307 - 308
in dichloromethane N2 atmosphere, addn. of soln. of borane to soln. of stannyl compound at -78°C (15 min), slow warming to room temp., stirring (room temp.,3 d); (5)B-NMR-monitoring, PhN(SnMe3)(BtBuBr)/tBu(Me)BBr ratio 2:3, not isolated;
参考文献
European Journal of Inorganic Chemistry, , # 9 p. 1765 - 1780
in neat (no solvent) equimolar amts. of Me3SnH and SiF2Cl2 room temp., 3.5 days; removing of Me3SnBr by trap coolingto -131°C, cooling to -196°C; not isolated; IR, (1)H-, (19)F-NMR spectroscopy (identified 5percent SiF3H, 5percent SiH4 and 5percent SiFCl2H in product mixt.);
