反应条件
in dichloromethane N2 atmosphere, addn. of soln. of stannyl compound to suspension of Me2SnCl2 at room temp., addn. of soln. of tBuBBr2 at -50°C (1.5 h), warming to room temp. (1.5 h), stirring (25°C, 96 h), reflux (48 h); removement of solvent (25°C, 12 Torr), condensation of Me3SnBr and Me2SnClBr in a trap (-78°C), distillation (48-51°C, 1E-5Torr), spectroscopic yields: (PhNBtBu)3 20percent; PhN(BtBuCl)2 80percent; elem. an al.;
参考文献
Diemer, Stefan; Noeth, Heinrich; Storch, Wolfgang
European Journal of Inorganic Chemistry, 1999 , # 9 p. 1765 - 1780
