in diethyl ether A soln. of HgCl2 in Et2O is added at room temp. during 20 min to a soln. of 1-phenyl-1,2-bis(trimethylstannyl)-ethene in Et2O (molar ratio 1:1)under an inert atmosphere.; A white solid separates immediately. Approximately 0.5 h later elemental Hg separates.;
参考文献
Journal of Organometallic Chemistry, , vol. 471, # 1-2 p. 39 - 42
in neat (no solvent) byproducts: (t-C4H9)(i-C3H7)PSiCl3, (t-C4H9)(i-C3H7)PSi2Cl5, (t-C4H9)(-i-C3H7)PH; N2 atmosphere, addn. of Si2Cl6 to ice-cooled stannyl compound, warming to room temp., 20 min; other reaction time; (29)Si- and (31)P-NMR-monitoring;
参考文献
European Journal of Inorganic Chemistry, , # 8 p. 1381 - 1392
in neat (no solvent) byproducts: propene, butene, hexene; hydride condensed onto palladium complex at 77 K and warmed slowly to room temp.; volatile products separated by trap-to-trap fractional distillation at 298 K, 253 K, 153 K and 77 K, fractions collected at each temp. dissolved in ether and solns. passed through gas chromatograph;
in methanol-d4 Irradiation (UV/VIS); 20°C; not isolated; (1)H-NMR spectroscopy;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 33, p. 2201 - 2201
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 33, p. 2406 - 2407
in tetrachloromethane Kinetics; excess of Mn-complex, 3 h; kinetic data at varying excess of Mn-complex,30.0-49.9°C; not isolated, detd. by IR and (1)H-NMR spectroscopy; kinetics followed by UV/VIS spectroscopy;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1024 - 1028
