diethyl ether
Erhitzen des Reaktionsprodukts ueber Aluminiumoxid bei 300grad und Hydrieren des erhaltenen Olefin-Gemisches an Raney-Nickel bei 250grad/250 at;
参考文献
Schlenk
Justus Liebigs Annalen der Chemie, 1951 , vol. 573, p. 142,158
in diethyl ether
ZnBr2 was dried for 3 h at 100°C in vac., cooled to room temp., dry diethyl ether was added under Ar, cooled to 5°C, i-PrMgCl was added, the mixt. was stirred at room temp. for 12 h under Ar; filtered under Ar, the residue was washed with pentane, reduced in vol.,distilled in vac.;
参考文献
Gridnev, Ilya D.; Serafimov, Joerg M.; Quiney, Harry; Brown, John M.
Organic and Biomolecular Chemistry, 2003 , vol. 1, # 21 p. 3811 - 3819
Zakharkin, L. I.; Pryanishnikov, A. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 2 p. 312 - 314
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 2 p. 349 - 350
in tetrahydrofuran; diethyl ether
T=0 - 20°C; Inert atmosphere;
参考文献
Lifchits, Olga; Mahlau, Manuel; Reisinger, Corinna M.; Lee, Anna; Fares, Christophe; Polyak, Iakov; Gopakumar, Gopinadhanpillai; Thiel, Walter; List, Benjamin
Journal of the American Chemical Society, 2013 , vol. 135, # 17 p. 6677 - 6693
