(C2D5)2OD(1+) in gas
T=57.9°C; experiment conditions: NBS pulsed ion cyclotron resonance; probability of a reactive H/D exchange encounter for the deuteronated ion as a function of the Gibbs free-energy change of the (endoergic) deuteron transfer reaction; Rate constantMechanismThermodynamic data;
参考文献
Lin, Shu-Kun; Jaun, Bernhard
Helvetica Chimica Acta, 1992 , vol. 75, # 5 p. 1478 - 1490