反应条件
1: 3-chloroprop-1-ene With Chromium (III) chloride; manganese; (1R,8S,9R,1'R,8'S,9'R)-2-[8'-(1-hydroxy-1-methylethyl)-10,10,10',10'-tetramethyl-[5,5']bi[6-azatricyclo[7.1.1.0(2,7)]undecyl]-2(7),3,5,2',4',6'-hexaen-8-yl]propan-2-ol; triethylamine in tetrahydrofuran
Nozaki-Hiyama reaction; 1 h; Inert atmosphere;
2: benzaldehyde With chloro-trimethyl-silane in tetrahydrofuran
Nozaki-Hiyama reaction; 24 h; Inert atmosphere;
3: With tetrabutyl ammonium fluoride in tetrahydrofuran
0.25 h; optical yield given as percent eeenantioselective reaction;
参考文献
Huang, Xin-Ren; Pan, Xin-Hong; Lee, Gene-Hsian; Chen, Chinpiao
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1949 - 1954
