n-C4H9Li in tetrahydrofuran; hexane Treating soln. of ClC2H4OH in THF (0°C) with n-BuLi (n-hexane) followed by Pt-compd., stirring of suspn. at 0°C for 20 min, and then reducing of volume.; Addn. of n-pentane, filtn., drying of soln., treating with Et2O. IR andGLC/MS spectra show presence of free oxazoline. Sepn. of Pt-compds. by taking advantage of the higher solubility of chloro complex in benzene. Elem. anal. of Pt-oxazoline compd.;
sodium hydroxide in water; acetone T=4.9°C; other temperature; Thermodynamic dataKineticsRate constant;
参考文献
Marchukov, V. A.; Nikitin, O. A.; V'yunov, K. A.; Ginak, A. I.
Journal of Organic Chemistry USSR (English Translation), 1983 , p. 2282 - 2286
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 12 p. 2600 - 2604
