n-butyllithium 1.) THF, -5-(-10) grad C, 30 min, nitrogen, 2.) THF, 1 h at -5-(-10) grad C then 24 h at room temp.; Yield given. Multistep reaction. Yields of byproduct given;
in gaseous matrix byproducts: C3H7; reaction of in situ generated Cl atoms (by microwave discharge from Cl2/He or Cl2/Ne mixt., Cl atom beam velocity 1150-1950 m/s) with alkyl iodide according to: S. M. A. Hoffmann, D. J. Smith, R. Grice, Mol. Phys. 49 (1983) 621; mass spectroscopy;
参考文献
Hoffmann, S. M. A.; Smith, D. J.; Gonzales Urenna, A.; Grice, R.
Chemical Physics Letters, 1984 , vol. 107, p. 99 - 102
Vincent
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1886 , vol. 103, p. 208
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Lebeau
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