water; anhydrous silver T=25°C; other metal ion (Hg2+); hydrolysis of primary alkyl halides with electrophilic assistance by metal ions, evidence for SN1 mechanism; Rate constantProduct distribution;
anhydrous magnesium perchlorate; water; Mercury T=298°C; 30 h; other metal ions; other electrolytes; Product distributionRate constantMechanism;
参考文献
Zamashchikov, V. V.; Bezbozhnaya, T. V.; Chanysheva, I. R.
Journal of Organic Chemistry USSR (English Translation), 1986 , p. 1029 - 1036
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 6 p. 1145 - 1153