hydroperoxide anion
P=0.3 Torr; Ambient temperatureabsence of an α-effect in the gas-phase nucleophilic reaction of reagent;
参考文献
DePuy, Charles H.; Della, Ernest W.; Filley, Jonathan; Grabowski, Joseph J.; Bierbaum, Veronica M.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2481 - 2482
18OH radical
P=0.3 Torr; Ambient temperatureabsence of an α-effect in the gas-phase nucleophilic reaction of reagent;
参考文献
DePuy, Charles H.; Della, Ernest W.; Filley, Jonathan; Grabowski, Joseph J.; Bierbaum, Veronica M.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2481 - 2482
potassium chloride; hydroxide in 1,4-dioxane; water
T=25°C; also for the pig liver esterase catalysed hydrolysis; Rate constant;
参考文献
Barton, Patrick; Laws, Andrew P.; Page, Michael I.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 9 p. 2021 - 2030
