carbon monoxide; butyric acid sodium salt in neat (no solvent)
mixt. of PdCl(C3H5), HCO2Me, Na butyrate (as nucleophile) stirred at room temp. for 30 min, addn. of CO, react. time 2 h; react. mixt. filtered, colourless liquid analysed by GLC;
参考文献
Keim; Becker; Kraneburg; Greven
Journal of molecular catalysis, 1989 , vol. 54, # 1 p. 37 - 43
water
T=20°C; different initial conc. of methyl formate, influence of temp. on the chemical equilibrium (T: 20 - 150 deg C); ΔH0, ΔS0; Equilibrium constantThermodynamic data;
参考文献
Gladii, S. L.; Starchevskii, M. K.; Pazderskii, Yu. A.; Moiseev, I. I.
J. Appl. Chem. USSR (Engl. Transl.), 1990 , vol. 63, # 1.2 p. 120 - 125,106 - 111