2,4,4-三甲基-1-戊烯合成路线 （共 303 条）
反应条件
1: concentrated sulfuric acid / 20 - 25 °C 2: aqueous methanol. KOH View Scheme
参考文献
Roehm and Haas Co.
Patent: US2008017 , 1932 ;
参考文献
I.G. Farbenind.
Patent: DE745802 , 1936 ;
DRP/DRBP Org.Chem.
反应条件
1: H2SO4 / acetic acid / 50 °C 2: bis-(4-isocyanato-phenyl)-methane, PhNH2, HCHO, COCl2 / 210 °C View Scheme
参考文献
Mueller,G.; Merten,R.
Chemische Berichte, 1965 , vol. 98, p. 1097 - 1110
参考文献
Luskin et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 4965
反应条件
borane; oxygen in tetrahydrofuran various temperatures, various oxygen stoichiometries, other olefines; Product distributionMechanism;
参考文献
Ziegler et al.
Justus Liebigs Annalen der Chemie, 1960 , vol. 629, p. 249
反应条件
sodium hydroxide; sodium tetrahydroborate; boron trifluoride diethyl etherate; dihydrogen peroxide 1.) diglyme, 25-35 deg C, 1 h; 2.) diglyme, 25-35 deg C; Yield given. Multistep reaction;
参考文献
Brown, Herbert C.; Snyder, Carl; Rao, B. C. Subba; Zweifel, George
Tetrahedron, 1986 , vol. 42, # 20 p. 5505 - 5510
反应条件
hydrogen fluoride T=0 - 6°C;
参考文献
Schlatter; Clark
Journal of the American Chemical Society, 1953 , vol. 75, p. 361,362
参考文献
Calcott; Tinker; Weinmayr
Journal of the American Chemical Society, 1939 , vol. 61, p. 1010,1014
Full Text Show Details
Schlatter; Clark
Journal of the American Chemical Society, 1953 , vol. 75, p. 361,362
反应条件
sulfuric acid T=105 - 115°C;
参考文献
Gunaratne, H. Q. Nimal; Lotz, Tobias J.; Seddon, Kenneth R.
New Journal of Chemistry, 2010 , vol. 34, # 9 p. 1821 - 1824
反应条件
1-butyl-3-methylimidazolium heptachlorodiindate (III) T=90 - 110°C; 2 h; In ionic liquid; Product distribution / selectivity;
参考文献
SCHENECTADY INTERNATIONAL, INC.
Patent: WO2006/74401 A1, 2006 ;
Location in patent: Page/Page column 26 ;
