2-甲基-2,4-戊二醇合成路线 （共 135 条）
反应条件
1.1: chloro-trimethyl-silane / dichloromethane / 20 °C / |Inert atmosphere
2.1: 9-borabicyclo[3.3.1]nonane dimer / toluene / 18 h / |Inert atmosphere; |Reflux
2.2: 1 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Soderquist, John A.; Kock, Iveliz; Estrella, Maria E.
Organic Process Research and Development, 2006 , vol. 10, # 5 p. 1076 - 1079
参考文献
Blicke; Anderson
Journal of the American Chemical Society, 1952 , vol. 74, p. 1733,1735
反应条件
1.1: 7 percent / HBr / H2O
2.1: i-PrMgCl / NiPy4Cl2 / tetrahydrofuran / 40 h / 20 °C
2.2: tetrahydrofuran
View Scheme
参考文献
Viktorov; Zubritskii
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 12 p. 1755 - 1765
参考文献
Mikhailov,B.M. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1976 , vol. 25, p. 1932 - 1938
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1976 , vol. 25, p. 2062 - 2069
参考文献
Winthrop Chem. Co.
Patent: US1837273 , 1930 ;
反应条件
hydrogen bromide; calcium chloride
T=30 - 35°C;
参考文献
I. G. Farbenind.
Patent: DE434989 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 1716
反应条件
1: HCl
2: KOtBu
View Scheme
参考文献
Mastagli,P.; Lagrange,G.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1968 , vol. 267, p. 1362 - 1364
参考文献
Winthrop Chem. Co.
Patent: US1837273 , 1930 ;
参考文献
Meyers,A.I. et al.
Journal of Organic Chemistry, 1973 , vol. 38, p. 2136 - 2143
反应条件
1: H2SO4
2: tetrahydrofuran; pentane
View Scheme
参考文献
Meyers,A.I. et al.
Journal of Organic Chemistry, 1973 , vol. 38, p. 2136 - 2143
