2,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷合成路线 （共 14 条）
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
1: n-butyllithium; [(η7–C7H6)Ti(η5–C5H4)](OSiMe2)(SiMe2) in tetrahydrofuran T=20°C; 2 h; 2: cyclo-(Me2SiO)3 With chloro-trimethyl-silane in tetrahydrofuran 2 h;
参考文献
Journal of Organometallic Chemistry, , vol. 751, p. 628 - 637
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷
参考文献
Journal of the American Chemical Society, , vol. 68, p. 360,363
Journal of the American Chemical Society, , vol. 63, p. 1195
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
H2O in water slow addn. of 4l (CH3)2SiCl2 to 12l H2O at 15-20°C withorous stirring; further products;; distn.;;
参考文献
Journal of the American Chemical Society, , vol. 68, p. 358 - 363
Si: MVol.C, 96, page 260 - 264
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
gallium triiodide T=175 - 180°C; 3 h; Yield givenFurther byproducts given. Title compound not separated from byproducts;
参考文献
Russian Journal of General Chemistry, , vol. 68, # 4 p. 656 - 657
Zhurnal Obshchei Khimii, , vol. 68, # 4 p. 697 - 698
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
phosphazene base T=150 - 165°C; P=7.50075 Torr; Product distribution / selectivity;
参考文献
WO2008/157020 A1, ;
Page/Page column 19-21 ;
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
tin; copper; zinc oxide T=325°C; 46 h; Product distribution / selectivity;
参考文献
US2007/249855 A1, ;
Page/Page column 19-20 ;
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
hydrogenchloride in toluene T=20°C; 4 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 60, # 9.2 p. 2100 - 2106,1873 - 1878
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
hydrogenchloride in toluene T=20°C; 4 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 60, # 9.2 p. 2100 - 2106,1873 - 1878
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷+
反应条件
iodine in dichloromethane 0.333333 h; Heating; Further byproducts given;
参考文献
Russian Journal of General Chemistry, , vol. 70, # 9 p. 1368 - 1370
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107-50-62,2,4,4,6,6,8,8,10,10,12,12,14,14-十四甲基-1,3,5,7,9,11,13-七氧杂-2,4,6,8,10,12,14-七硅杂环十四烷
