sulfuric acid; antimony pentachloride in tetrachloromethane; sulfuric acid shaking of (CH3)3SiOSi(CH3)3 and ((CH3)2SiO)4 (1:1 mol) with concd. H2SO4 at 25°C for 8 days; equilibrium react.; further products;;
H2SO4 in sulfuric acid aq. H2SO4; shaking of (CH3)3SiOSi(CH3)3 and ((CH3)2SiO)4 with concd. H2SO4 at room temp. for 4 h;;
参考文献
Patnode, W. I.; Wilcock, D. F.
Journal of the American Chemical Society, 1946 , vol. 68, p. 358 - 363
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Gmelin Handbook: Si: MVol.C, 103, page 282 - 285
Voronkov, M. G.; Tsyrendorzhieva, I. P.; Albanov, A. I.; Shergina, N. I.; Klyba, L. V.; Dubinskaya, E. I.
Russian Journal of General Chemistry, 1998 , vol. 68, # 4 p. 654 - 655
Zhurnal Obshchei Khimii, 1998 , vol. 68, # 4 p. 695 - 696
Patnode; Wilcock
Journal of the American Chemical Society, 1946 , vol. 68, p. 360,363
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Scott
Journal of the American Chemical Society, 1946 , vol. 68, p. 2295
NaOH in water byproducts: C2H5OH; heating of (CH3)2Si(OC2H5)2, (CH3)3Si(OC2H5) and an excess (50percent) of H2O in presence of NaOH; sepn. of C2H5OH by distn.; boiling of the residue with 20percent aq. HCl; further products;; distn.;;
参考文献
Hunter, M. J.; Warrick, E. L.; Hyde, J. F.; Currie, C. C.
Journal of the American Chemical Society, 1946 , vol. 68, p. 2284 - 2290
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Gmelin Handbook: Si: MVol.C, 103, page 282 - 285
water in toluene T=20°C; 27 h; Further byproducts given;
参考文献
Kopylov, V. M.; Agashkov, S. P.; Sunkovich, G. V.; Prikhod'ko, P. L.
J. Gen. Chem. USSR (Engl. Transl.), 1991 , vol. 61, # 6.2 p. 1378 - 1383,1257 - 1261
aluminium(III) iodide T=140 - 170°C; 5 h; Yield givenTitle compound not separated from byproducts;
参考文献
Voronkov, M. G.; Tsyrendorzhieva, I. P.; Albanov, A. I.; Shergina, N. I.; Klyba, L. V.; Dubinskaya, E. I.
Russian Journal of General Chemistry, 1998 , vol. 68, # 4 p. 654 - 655
Zhurnal Obshchei Khimii, 1998 , vol. 68, # 4 p. 695 - 696
sodium nitrate; 1,1,1,3,3,3-hexamethyl-disilazane T=20°C; 2 h; Yield givenFurther byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Voronkov, M. G.; Tsyrendorzhieva, I. P.; Ivanova, N. P.; Dubinskaya, E. I.
Russian Journal of General Chemistry, 1998 , vol. 68, # 4 p. 658 - 659
Zhurnal Obshchei Khimii, 1998 , vol. 68, # 4 p. 699 - 700
