Ag2(4,4'-bipy)2(O3SCH2CH2SO3)*4H2O-based polymer in toluene
T=110°C;
参考文献
Fei, Honghan; Paw U, Latisha; Rogow, David L.; Bresler, Marc R.; Abdollahian, Yashar A.; Oliver, Scott R. J.
Chemistry of Materials, 2010 , vol. 22, # 6 p. 2027 - 2032
potassium hydroxide; sodium periodate; ruthenium trichloride in water
T=60°C; other temp. (40 deg C, 80 deg C); var. periodate conc., substrat conc., alkali conc.; (Ru(III)); KCl; ΔH(excit.), ΔS(excit.); Rate constantMechanism;
参考文献
Harrison, Phillip G.; Maunders, Barry M.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1984 , vol. 80, p. 1329 - 1340
1: 66 percent / Sodium hydride(50percent in oil) / diethyl ether / 5 h / Heating
2: cc. H2SO4 / acetic acid / 240 h / Ambient temperature
3: 22 percent / 10percent aq. potassium hydroxide / 1.5 h / 0 °C
View Scheme
参考文献
Crombie, Leslie; Jones, Raymond C. F.; Palmer, Christopher J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 317 - 332