1: With lithium aluminium tetrahydride in tetrahydrofuran T=0 - 60°C; 72 h; Inert atmosphere; 2: With water in tetrahydrofuran T=0°C; 0.5 h; Inert atmosphere;
1: With hydrogen; dicobalt octacarbonyl; dppmO in toluene T=100°C; Ring cleavage; Hydroformylation; P=75007.5 Torr; 4 h; 2: Hydrogenation; Further stages.;
参考文献
Weber; Englert; Ganter; Keim; Moethrath
Chemical Communications, 2000 , # 15 p. 1419 - 1420
sodium hydroxide; hydrogen; solid catalyst similar to the "G" catalyst disclosed in U.S. Pat. No. 6,479,713 or the "HC-1" catalyst available from Sud Chemie (Louisville, Ky.) in water T=184 - 206°C; P=82745.9 Torr; Product distribution / selectivity;
sodium hydroxide; hydrogen; solid catalyst similar to the "G" catalyst disclosed in U.S. Pat. No. 6,479,713 or the "HC-1" catalyst available from Sud Chemie (Louisville, Ky.) in water T=178 - 196°C; P=82745.9 Torr; Product distribution / selectivity;
