1,1,1,3-四氯丙烷合成路线 （共 77 条）
反应条件
pentacarbonyliron(0); cyclohexanol
T=130 - 140°C; 3.5 h; further reagents, percent of conversion; Product distribution;
参考文献
Chukovskaya, E. Ts.; Rozhkova, M. A.; Freidlina, R. Kh.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 7 p. 1406 - 1409
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 7 p. 1582 - 1585
反应条件
trans-Mo(N2)2(1,2-bis(diphenylphosphino)ethane)2 in acetonitrile
T=140°C; 3 h; further reagents Mo(CO)6, Mo(CO)5PPh3, cis-Mo(CO)4(PPh3)2, cis-Mo(CO)4(dppe), cis-Mo(CO)2(dppe)2, MoH4(dppe)2;
参考文献
Zhiryukhina, N. P.; Chukovskaya, E. Ts.; Makhaev, V. D.; Borisov, A. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 3 p. 539 - 542
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 3 p. 600 - 603
反应条件
2-chloro-1-propene; hexacarbonyl molybdenum; isopropyl alcohol
T=140°C; 3 h; Heating;
参考文献
Zhiryukhina, N. P.; Chukovskaya, E. Ts.; Makhaev, V. D.; Borisov, A. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 3 p. 539 - 542
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 3 p. 600 - 603
反应条件
hexacarbonyl molybdenum; isopropyl alcohol
T=140°C; 3 h; Heating;
参考文献
Zhiryukhina, N. P.; Chukovskaya, E. Ts.; Makhaev, V. D.; Borisov, A. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 3 p. 539 - 542
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 3 p. 600 - 603
反应条件
pentacarbonyliron(0); cyclohexanol
T=130 - 140°C; 3.5 h; further reagents, percent of conversion, ratio between paths of reaction; Product distributionMechanism;
参考文献
Chukovskaya, E. Ts.; Rozhkova, M. A.; Freidlina, R. Kh.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 7 p. 1406 - 1409
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 7 p. 1582 - 1585
反应条件
pentacarbonyliron(0)
T=120°C; 3 h; reaction of 1,1,1,3-tetrachloropropane with 1-hexene initiated by Fe(CO)5, Mo(CO)5 and Mn2(CO)10, conversion, effect of the nature of metal carbonyls, solvents; Product distribution;
参考文献
Chukovskaya, E. Ts.; Kuz'mina, N. A.; Rozhkova, M. A.; Freidlina, R. Kh.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 6 p. 1198 - 1202
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 6 p. 1345 - 1349
参考文献
U.S.Rubber Co.
Patent: US2725411 , 1948 ;
反应条件
2-ethoxy-ethanol; potassium hydroxide
T=80°C;
参考文献
DAIKIN INDUSTRIES, LTD.; NOSE, Masatoshi; SUZUKI, Atsushi; YAMASHITA, Tsuneo; KATSUKAWA, Kenichi
Patent: WO2010/123148 A1, 2010 ;
Location in patent: Page/Page column 10; 11 ;
反应条件
anhydrous iron chloride; chlorine
T=82°C; P=1277.21 Torr; 15.33 h; Product distribution / selectivity;
参考文献
OCCIDENTAL CHEMICAL CORPORATION
Patent: WO2009/85862 A1, 2009 ;
Location in patent: Page/Page column 28 ;
参考文献
Nesmejanow; Semenow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 2119; engl. Ausg. S. 2022
