1: 4-chloro-1-ethenylbenzene With magnesium in tetrahydrofuran
2: With zinc(II) chloride in tetrahydrofuran
T=20°C;
3: 2,6-dibromo-4-methyl-benzenamine With dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; tris-(dibenzylideneacetone)dipalladium(0) in tetrahydrofuran
Negishi coupling reaction; 12 h; Reflux;
参考文献
Popeney, Chris S.; Levins, Chris M.; Guan, Zhibin
Organometallics, 2011 , vol. 30, # 8 p. 2432 - 2452
bis[.eta.(3)-allyl(chloro)nickel(II)]; Na[B(3,5-(CF3)2C6H3)4] in dichloromethane
T=-30°C; P=750.075 Torr; 4 h; Title compound not separated from byproducts.;
参考文献
Francio, Giancarlo; Faraone, Felice; Leitner, Walter
Journal of the American Chemical Society, 2002 , vol. 124, # 5 p. 736 - 737
tert-butylhypochlorite; lithium iodide in dichloromethane
T=20°C; 24 h; Inert atmosphere;
参考文献
Yoshimura, Akira; Koski, Steven R.; Kastern, Brent J.; Fuchs, Jonathan M.; Jones, T. Nicholas; Yusubova, Roza Y.; Nemykin, Victor N.; Zhdankin, Viktor V.
Chemistry - A European Journal, 2014 , vol. 20, # 20 p. 5895 - 5898
