K-Na; [15]crown-5 in benzene-d6
crown ether was added to K-Na alloy in C6D6 under Ar followed by addn. of a soln. of bromodiazaborole in C6D6, mixt. was stirred at room temp.; NMR spectral data;
参考文献
Weber; Schnieder; Loennecke
Journal of the Chemical Society, Dalton Transactions, 2001 , # 23 p. 3459 - 3464
Baskir, E. G.; Maltsev, A. K.; Korolev, V. A.; Khabashesku, V. N.; Nefedov, O. M.
Russian Chemical Bulletin, 1993 , vol. 42, # 8 p. 1438 - 1440
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 8 p. 1499 - 1502
in benzene-d6
Kinetics; soln. of (C5Me5)2SmMe(THF) in C6D6 prepared in NMR-tube, tube cooled in a liquid nitrogen-bath, evacuated and sealed; after 6 days at room temp. complete convertion;; monitored by (1)H-NMR-spectroscopy;;
参考文献
Evans,W.J.; Chamberlain,L.; Ulibarri,T.
Journal of the American Chemical Society, 1988 , vol. 110, p. 6423
