3,3-dimethyldioxirane in dichloromethane; acetone T=20°C; 2 h; Yield given. Yields of byproduct given;

3,3-dimethyldioxirane in dichloromethane; acetone T=20°C; 2 h; Yield given. Yields of byproduct given;

1: 41 percent / isopentyl nitrite / acetone; CH2Cl2 / 0.5 h 2: 94 percent / Heating 3: 66 percent / zinc dust, sodium chloride, water / 3 h / 150 °C / Heating 4: zinc dust, sodium chloride, water / 2 h / 240 °C View Scheme

1: 41 percent / isopentyl nitrite / acetone; CH2Cl2 / 0.5 h 2: 94 percent / Heating 3: 66 percent / zinc dust, sodium chloride, water / 3 h / 150 °C / Heating View Scheme

1: 41 percent / isopentyl nitrite / acetone; CH2Cl2 / 0.5 h 2: 94 percent / Heating View Scheme

With  hydrogenchloride  Behandeln der wss.Reaktionsloesung mit Silbernitrat;