1: 4-tert-butylaniline With n-butyllithium in hexane; chlorobenzene T=0 - 20°C; 2: With zinc(II) chloride−TMEDA in hexane; chlorobenzene 3: PhZnPh With iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane in hexane; chlorobenzene T=80°C; 15 h;
1: benzaldehyde With ammonia in methanol T=20°C; 12 h; 2: PhZnPh in toluene T=-78°C; 1 h; 3: With water; sodium hydrogencarbonate in toluene T=20°C; Product distribution / selectivity;
参考文献
KANATA CHEMICAL TECHNOLOGIES INC.
Patent: WO2008/119162 A1, 2008 ;
Location in patent: Page/Page column 48 ;
