1: α-bromo-methylpyridine With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran; diethyl ether; pentane
T=-115°C; Inert atmosphere;
2: chloro-diphenylphosphine in tetrahydrofuran; diethyl ether; pentane
T=-70°C; Inert atmosphere;
参考文献
Goudriaan, P. Elsbeth; Jang, Xiao-Bin; Kuil, Mark; Lemmens, Renske; Van Leeuwen, Piet W. N. M.; Reek, Joost N. H.
European Journal of Organic Chemistry, 2008 , # 36 p. 6079 - 6092
1: cyclobenzothiazole With (TMP)2Zn*2MgCl2*2LiCl in tetrahydrofuran
T=25°C; 0.5 h;
2: chloro-diphenylphosphine in tetrahydrofuran
T=25°C; 5 h; Further stages.;
参考文献
Wunderlich, Stefan H.; Knochel, Paul
Angewandte Chemie - International Edition, 2007 , vol. 46, # 40 p. 7685 - 7688
