in hydrogenchloride; water
(CH3)2NCH2CH2NH2 in 0.1M HCl was added dropwise with stirring to a hot soln. of Pt-complex in H2O, stirring for 10 min; refrigerated overnight, filtered, washed (H2O), dried in vacuo;
参考文献
Berners-Price, Susan J.; Frey, Urban; Ranford, John D.; Sadler, Peter J.
Journal of the American Chemical Society, 1993 , vol. 115, # 19 p. 8649 - 8659
in water
K2PtCl4 dissolved in boiling water; cooled; ligand (10percent excess) added; after 1 h ppt. filtered; recrystd. (hot water contg. some HCl); filtrateconcd. on rotary evaporator; Pt(NH3)4Cl2 added; mixt. heated with stirr ing; Pt(NH3)4PtCl4 collected on filter; ppt. was obtained from filtrate;washed (aq. HCl, EtOH); elem. anal.;
参考文献
Fedotova; Aleksandrov; Kuznetsova
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 12 p. 1862 - 1869
