反应条件
1: potassium carbonate / acetone / 20 °C
2: osmium(VIII) oxide; sodium periodate; 2,6-dimethylpyridine / 1,4-dioxane; water / 3 h / 20 °C
3: (+)-6,6'-(((1R,2R,4R,5R)-bicyclo[2.2.2]octane-2,5-diylbis(azanediyl))bis(methylene))bis(2,4-di-tert-butylphenol); (CuOTf)2*C6H5CH3 / methanol / 40 °C / |Molecular sieve
4: hydrogen; palladium on activated charcoal / methanol / 20 °C / 760.05 Torr
View Scheme
参考文献
Ohta, Hiromichi; Miyamae, Yoshitaka; Tsuchihashi, Gen-ichi
Agricultural and Biological Chemistry, 1986 , vol. 50, # 12 p. 3181 - 3184
