1: 77 percent / bromine, aluminium powder
2: 83 percent / aluminium chloride / benzene / 0.5 h / Heating
3: 22 percent / nitric acid, acetic acid / 4 h / 15 - 16 °C / further nitration agents
4: potassium carbonate / dimethylformamide / Ambient temperature
5: 77 percent / potassium carbonate, copper(II) oxide / 16 h / 140 °C
6: 97 percent / bromine / CH2Cl2 / 0.25 h
7: 85 percent / bromine / CH2Cl2 / 19.5 h
8: 95 percent / phosphinic acid / palladized charcoal / methanol / 0.42 h / Heating
9: 1.) sodium nitrite, hydrochloric acid, 2.) phosphinic acid / 1.) dioxane, water, 0 - 5 deg C, 0.5 h, 2.) 21 h
10: 48 percent / copper bronze / 2 h / 260 °C
11: 98 percent / potassium hydroxide, water / dimethylsulfoxide / 1.67 h / Heating
12: 11 percent / copper chromite / quinoline / 1.5 h / 180 °C
View Scheme
参考文献
Carvalho, Christopher F.; Sargent, Melvyn V.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1613 - 1620
Wyatt, Emma E.; Fergus, Suzanne; Galloway, Warren R. J. D.; Bender, Andreas; Fox, David J.; Plowright, Alleyn T.; Jessiman, Alan S.; Welch, Martin; Spring, David R.
Chemical Communications, 2006 , # 31 p. 3296 - 3298
