in benzene React. of 3 equiv of org. compd. with stirred suspn. of Mo-complex in benzene (25°C, inert-atmosphere).; Removal of benzene, unreacted phosphine and mes after 48 h in vac., dissolving of resulting materials in benzene and passing of soln. through alumina column. Removal of benzene (vac.) gives pure complex as viscous oil.; elem. anal.;
参考文献
Diel, Bruce N.; Brandt, Paul F.; Haltiwanger, Curtis R.; Hackney, Michael L. J.; Norman, Arlan D.
Inorganic Chemistry, 1989 , vol. 28, p. 2811 - 2816
in benzene React. of 3 equiv of org. compd. with stirred suspn. of Mo-complex in benzene (25°C, inert-atmosphere).; Removal of benzene, unreacted phosphine and mes after 48 h in vac., dissolving of resulting materials in benzene and passing of soln. through alumina column. Removal of benzene (vac.), crystn. from toluene.;
参考文献
Diel, Bruce N.; Brandt, Paul F.; Haltiwanger, Curtis R.; Hackney, Michael L. J.; Norman, Arlan D.
Inorganic Chemistry, 1989 , vol. 28, p. 2811 - 2816
in benzene React. of 3 equiv of org. compd. with stirred suspn. of Mo-complex in benzene (25°C, inert-atmosphere).; Removal of benzene, unreacted phosphine and mes after 48 h in vac., dissolving of resulting materials in benzene and passing of soln. through alumina column. Removal of benzene (vac.) gives pure complex as viscous oil.;
参考文献
Diel, Bruce N.; Brandt, Paul F.; Haltiwanger, Curtis R.; Hackney, Michael L. J.; Norman, Arlan D.
Inorganic Chemistry, 1989 , vol. 28, p. 2811 - 2816
CH3Li in tetrahydrofuran; diethyl ether (Ar); CH3Li in Et2O added dropwise to ((CH3)3Sn)3C6H3 in THF (-70°C); warmed to -50°C, stirred; (CH3)2SO4 added; further product;further intermediates; various yields of intermediates at various reactant ratios and addition orders; CH3OD added; warmed to room temp.; water and C6(CH3)6 added; extd. (Et2O); washed (water, brine); dried (MgSO4); identified by gas chromy.-massspectrometry; yields detd. by gas chromy.;
参考文献
Journal of Organometallic Chemistry, , vol. 593-594, p. 369 - 379
