lithium trifluoroacetate in trifluoroacetic acid
Kinetics; byproducts: CF3COOH; solns. of Tl(OCOCF3)3, arene, and CF3COOLi in degassed CF3COOH were mixed at 25°C under Ar in the dark, mixt. was stirred for a few min; rate consts. in the presence and in the absence of added CF3COOLi are given; solvent was removed in vacuo, residue identified by its (1)H NMR spectrum and via quant. converting into the corresponding iodide with KI followed by GC anal.;
参考文献
Lau, W.; Kochi, J. K.
Journal of the American Chemical Society, 1984 , vol. 106, # 23 p. 7100 - 7112
hexafluoroisopropyl alcohol
T=180°C; 43 h; Further byproducts given;
参考文献
Abramovitch, Rudolph A.; Evertz, Kaspar; Huttner, Gottfried; Gibson, Harry H. Jr.; Weems, Harold G.
Journal of the Chemical Society, Chemical Communications, 1988 , # 4 p. 325 - 327
