1-氨基-3,5-二甲苯合成路线 （共 187 条）
参考文献
Chemische Berichte, , vol. 18, p. 362
Chemische Berichte, , vol. 18, p. 2677,2681
反应条件
1.1: 95 percent / boric acid / toluene / 18 h / Heating 2.1: NaOH / butan-2-one / 50 °C 2.2: 84 percent / butan-2-one / 50 °C View Scheme
参考文献
Synthetic Communications, , vol. 36, # 15 p. 2129 - 2133
反应条件
tert.-butylhydroperoxide; cobalt(II)salen in dichloromethane; water T=23°C; 8 h;
参考文献
Journal of Organic Chemistry, , vol. 61, # 10 p. 3320 - 3326
反应条件
dihydrogen peroxide; lt;π-C5H5N(1+)(CH2)15CH3gt;3lt;PO4lt;W(O)(O2)2gt;4gt;(3-) in chloroform 2 h; Ambient temperature;
参考文献
Journal of Organic Chemistry, , vol. 58, # 14 p. 3633 - 3638
反应条件
acetic acid Cyclization; Paal-Knorr reaction; Heating;
参考文献
Journal of the Chemical Society. Perkin Transactions 2, , # 10 p. 2109 - 2116
反应条件
1: 1.) aq. HCl, NaNO2, 2.) NaOAc / 1.) 0 deg C, 1 h, 2.) H2O, 1 h, RT 2: 98 percent / aq. NaOH / ethanol / 3 h / Ambient temperature 3: 1.) LDA / 1.) THF, cyclohexane, 1 h, 2.) THF, cyclohexane, -70 deg C, 1 h View Scheme
参考文献
Kim, Dae-Kee; Kim, Young-Woo; Gam, Jongsik; Kim, Ganghyeok; Lim, Jinsoo; Lee, Namkyu; Kim, Hun-Taek; Kim, Key H.
Journal of Heterocyclic Chemistry, 1996 , vol. 33, # 4 p. 1275 - 1283
反应条件
1: 1.) aq. HCl, NaNO2, 2.) NaOAc / 1.) 0 deg C, 1 h, 2.) H2O, 1 h, RT 2: 98 percent / aq. NaOH / ethanol / 3 h / Ambient temperature 3: 1.) LDA / 1.) THF, cyclohexane, 1 h, 2.) THF, cyclohexane, -70 deg C, 1 h View Scheme
参考文献
Kim, Dae-Kee; Kim, Young-Woo; Gam, Jongsik; Kim, Ganghyeok; Lim, Jinsoo; Lee, Namkyu; Kim, Hun-Taek; Kim, Key H.
Journal of Heterocyclic Chemistry, 1996 , vol. 33, # 4 p. 1275 - 1283
反应条件
(i) NaNO2, aq. HCl, (ii) SO2, CuCl2, KCl, benzene, dioxane; Multistep reaction;
参考文献
Prinsen,A.J.; Cerfontain,H.
Recueil des Travaux Chimiques des Pays-Bas, 1965 , vol. 84, p. 24 - 30
反应条件
hydrogenchloride; sodium carbonate; sodium nitrite 1.) 0 deg C, 2.) reflux, 0.5 h; Yield given. Multistep reaction;
参考文献
Karlin, Kenneth D.; Nasir, M. Sarwar; Cohen, Brett I.; Cruse, Richard W.; Kaderli, Susan; Zuberbuehler, Andreas D.
Journal of the American Chemical Society, 1994 , vol. 116, # 4 p. 1324 - 1336
反应条件
ueber die Diazonium-Verbindung;
参考文献
Kohlrausch; Pongratz
Monatshefte fuer Chemie, 1934 , vol. 64, p. 361,364, 365
Monatshefte fuer Chemie, 1935 , vol. 65, p. 6,14
