1-氨基-3,5-二甲苯合成路线 （共 187 条）
反应条件
1: (3,5-dimethylphenyl)-(7-methoxymethyl-[1,4]-dioxano[2,3-g]quinazolin-4-yl)-amine With copper diacetate in acetonitrile T=-5°C; 0.25 h; 2: With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in acetonitrile T=-5°C; 0.0833333 h; 3: phenylhydrazine in acetonitrile T=-5°C; 3.33333 h;
参考文献
Jadhav, Ravindra R.; Huddar, Sameerana N.; Akamanchi, Krishnacharya G.
European Journal of Organic Chemistry, 2013 , # 30 p. 6779 - 6783
反应条件
1: copper; potassium carbonate 2: zinc View Scheme
参考文献
Fries; Boeker; Wallbaum
Justus Liebigs Annalen der Chemie, 1934 , vol. 509, p. 73,100
参考文献
Ribelles, Pascual; Sridharan, Vellaisamy; Villacampa, Mercedes; Ramos, M. Teresa; Menendez, J. Carlos
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 4 p. 569 - 579
反应条件
ruthenium trichloride; triphenylphosphine; tin(ll) chloride in 1,4-dioxane; acetone T=180°C; Condensation; 20 h;
参考文献
Cho, Chan Sik; Oh, Byoung Ho; Shim, Sang Chul
Journal of Heterocyclic Chemistry, 1999 , vol. 36, # 5 p. 1175 - 1178
反应条件
1,3-dimethyl-5-nitrobenzene; sulfuric acid; iron(II) sulfate
参考文献
Borsche; Groth
Justus Liebigs Annalen der Chemie, 1941 , vol. 549, p. 238,249
Full Text Show Details
Manske et al.
Canadian Journal of Research, Section B: Chemical Sciences, 1942 , vol. 20, p. 133,135
反应条件
1: sulfuric acid / Diazotization.Umsetzung der Diazoniumverbindung mit SO2 und Kupfer 2: potassium permanganate View Scheme
参考文献
Moschner
Chemische Berichte, 1901 , vol. 34, p. 1259
反应条件
ammonia; acetic acid T=70°C; 24 h;
参考文献
Vogel, Carola S.; Heinemann, Frank W.; Khusniyarov, Marat M.; Meyer, Karsten
Inorganica Chimica Acta, 2010 , vol. 364, # 1 p. 226 - 237
反应条件
in acetonitrile-D3 T=57°C; Kinetics;
参考文献
Frischmann, Peter D.; Jiang, Jian; Hui, Joseph K.-H.; Grzybowski, Joseph J.; MacLachlan, Mark J.
Organic Letters, 2008 , vol. 10, # 6 p. 1255 - 1258
反应条件
in acetonitrile-D3 T=57°C; Kinetics;
参考文献
Frischmann, Peter D.; Jiang, Jian; Hui, Joseph K.-H.; Grzybowski, Joseph J.; MacLachlan, Mark J.
Organic Letters, 2008 , vol. 10, # 6 p. 1255 - 1258
反应条件
1: With nitrogen(IV) oxide in acetonitrile T=-20°C; Diazotization; 2: With calcium bis(hypophosphite); Fe2SO4*7H2O in methanol; acetonitrile T=20°C; Dediazonation;
参考文献
Mitsuhashi, Hirokazu; Kawakami, Takehiko; Suzuki, Hitomi
Tetrahedron Letters, 2000 , vol. 41, # 29 p. 5567 - 5569
