1,2,3,4,5-五甲基-2,4-环戊二烯-1-甲酰氯合成路线 （共 8 条）
反应条件
1: 1.) n-BuLi / 1.) THF, 25 deg C, 0.5 h, 2.) from -60 to 25 deg C, 2: PCl5 / diethyl ether / 12 h / 25 °C View Scheme
参考文献
Kohl, Franz X.; Jutzi, Peter
Chemische Berichte, 1987 , vol. 120, p. 1539 - 1544
反应条件
thionyl chloride in Petroleum ether 2 h; Heating; Yield given;
参考文献
Kohl, Franz X.; Jutzi, Peter
Chemische Berichte, 1987 , vol. 120, p. 1539 - 1544
反应条件
1: 91 percent / 1) 1,3-cyclopentadiene, 1.36M BuLi / tetrahydrofuran; hexane 2: 1) 1.48M BuLi / 1) THF, hexane 3: thionylchloride / petroleum ether / 2 h / Heating View Scheme
参考文献
Kohl, Franz X.; Jutzi, Peter
Chemische Berichte, 1987 , vol. 120, p. 1539 - 1544
反应条件
n-butyllithium 1.) hexane, RT, 12 h, 2.) toluene, RT, 4 h; Yield given. Multistep reaction;
参考文献
Jutzi, Peter; Schwartzen, Karl-Heinz; Mix, Andreas; Stammler, Hans-Georg; Neumann, Beate
Chemische Berichte, 1993 , vol. 126, # 2 p. 415 - 420
反应条件
thionyl chloride 5 h; Heating; Yield given. Yields of byproduct given;
参考文献
Kohl, Franz X.; Jutzi, Peter
Chemische Berichte, 1987 , vol. 120, p. 1539 - 1544
反应条件
1: 24 percent / 1) Me5C5H, 1,48M BuLi / tetrahydrofuran; hexane 2: 91 percent / 1) 1,3-cyclopentadiene, 1.36M BuLi / tetrahydrofuran; hexane View Scheme
参考文献
Kohl, Franz X.; Jutzi, Peter
Chemische Berichte, 1987 , vol. 120, p. 1539 - 1544
反应条件
1: 24 percent / 1) Me5C5H, 1,48M BuLi / tetrahydrofuran; hexane 2: 91 percent / 1) 1,3-cyclopentadiene, 1.36M BuLi / tetrahydrofuran; hexane 3: 1.48M BuLi / tetrahydrofuran; hexane View Scheme
参考文献
Kohl, Franz X.; Jutzi, Peter
Chemische Berichte, 1987 , vol. 120, p. 1539 - 1544
反应条件
n-butyllithium; 1,2,3,4,5-pentamethylcyclopentadiene in tetrahydrofuran; hexane
参考文献
Kohl, Franz X.; Jutzi, Peter
Chemische Berichte, 1987 , vol. 120, p. 1539 - 1544
