反应条件
chloro-trimethyl-silane in diethyl ether
byproducts: (CH3)3SiH; (Schlenk, N2) (CH3)3SiCl in diethyl ether was added dropwise with stirring at -78°C to a soln. of complex and cyclohexene in diethyl ether, allowed to warm to room temp., stirred for 1 h,; filtered, washed with diethyl ether, evapd. to dryness under vac., dissolved in min warm heptane, the soln. was stored at -30°C for 12 h;elem. anal.;
参考文献
Scheibitz, Matthias; Li, Haiyan; Schnorr, Jan; Perucha, Alejandro Sanchez; Bolte, Michael; Lerner, Hans-Wolfram; Jaekle, Frieder; Wagner, Matthias
Journal of the American Chemical Society, 2009 , vol. 131, # 44 p. 16319 - 16329
