1: 2-bromo-pyridine With isopropylmagnesium chloride in tetrahydrofuran T=30°C; 3.5 h; 2: With zinc(II) chloride in tetrahydrofuran T=20°C; 1.66667 h; 3: para-amino-iodo-benzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran 24 h; Reflux;
参考文献
Muntaner, Jaime G.; Casarrubios, Luis; Sierra, Miguel A.
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 2 p. 286 - 297
sodium thiosulfate in ethanol; water 22 h; Heatingstarting pH=3.2, (85percent H3PO4, NaH2PO4);
参考文献
Foye, William O.; Abood, Norman; Kauffman, Joel M.; Kim, Young-Ho; Patel, Bhupendra R.
Phosphorus and Sulfur and the Related Elements, 1980 , vol. 8, p. 205 - 208