1.1: Te / hexane; tetrahydrofuran / 0.17 h / 20 °C 1.2: 70 percent / hexane; tetrahydrofuran / 92 h / Heating 2.1: Me2Cu(CN)Li2 / diethyl ether; tetrahydrofuran / 1.5 h / -20 °C 2.2: 41 percent / diethyl ether; tetrahydrofuran / 20 h / 20 °C View Scheme
参考文献
Kondo, Yoshinori; Shilai, Manabu; Uchiyama, Masanobu; Sakamoto, Takao
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 15 p. 1781 - 1782
1: 2-bromo-pyridine With isopropylmagnesium chloride in tetrahydrofuran T=20°C; 4 h; Inert atmosphereCooling with ice; 2: With zinc(II) chloride in tetrahydrofuran T=20°C; 2 h; Inert atmosphereCooling with ice; 3: para-chloro-benzonitrile Further stages;
参考文献
Colombe, James R.; Bernhardt, Sebastian; Stathakis, Christos; Buchwald, Stephen L.; Knochel, Paul
Organic Letters, 2013 , vol. 15, # 22 p. 5754 - 5757